Nanofibrillar PEDOT Mats for Impact-Resistant Shatterproof Supercapacitors
By Washington University of St.Louis
Posted On 29.4.2019
Source: Royal Society of Chemistry article; Washington University in St. Louis news
Researchers at Washington University in St. Louis made an energy storage device that can withstand a hammer striking it more than 40 times. The shatterproof supercapacitor is also nonflammable, unlike lithium-ion batteries. The new work is the cover story of the April 23 issue of the journal Sustainable Energy and Fuels.
“Accidentally dropping electronics, such as a laptop or cellphone, is a common scenario that may lead to the failure of the device,” said Julio D’Arcy, assistant professor of chemistry in Arts & Sciences. “In some cases, energy storage devices catch on fire due to impact-caused failure. The chance of impact damage will only increase as electronics become more flexible and worn on the human body.”
Hongmin Wang, a PhD candidate in chemistry who works in D’Arcy’s lab, led the effort to create the new material.
By controlling the formation of rust in solution, researchers grew a micrometer-thick porous mat of conducting fibers affixed to a soft, pliable layer of organic plastic. The result is somewhat similar to an open-faced sandwich.
“This is the same mechanism that is responsible for the formation of rust on the surface of a wet piece of steel,” D’Arcy said. “Here, we have carefully designed the nanostructure orientation so that a polymer film assembles parallel to a rusted surface. It produces an interwoven mat of polymer nanofibers with a textile-like structure that is flexible and ideal for storing energy in a supercapacitor.”
The researchers bent their new material to different angles over and over again. They hammered it repeatedly, and they also tested it against an impact equivalent to a car collision at 30 mph. The same amount of impact would fracture other materials such as metal and carbon.
The device held up well against these extreme tests: after the first hammer strike, it retained 80 percent of its ability to store energy at peak efficiencies; after 40 repeated strikes, it was still at 74 percent.
Abstract of article “Self-woven nanofibrillar PEDOT mats for impact-resistant supercapacitors” published in Royal Society of Chemistry journal:
Here, we demonstrate a nanoengineering strategy that leads to an impact-resistant electrode for flexible energy storage devices such as supercapacitors resulting in state-of-the-art electrochemical performance. A template-less direct vapor synthesis produces a mat of poly(3,4-ethylenedioxythiophene) (PEDOT) 1D nanostructures. A nucleation-controlled self-weaving mechanism is supported enabling rapid synthesis of an electrochemically active flexible electrode in a single step from the vapor phase.
Nanofibres self-assemble and “weave” in situ into a micrometer thick porous fibrillar mat characterized by a horizontally-directed interwoven nanofibrillar orientation. A nanofibrillar PEDOT mat is characterized by high conductivity (334 S cm−1), capacitance (164 F g−1) and flexibility (stable upon bending) as well as impact-resistance properties enabling it to withstand an impact energy density of 125 kJ m−2 and to continue storing energy. After a single 125 kJ m−2 mechanical impact, a symmetric electrochemical capacitor composed of nanofibrillar PEDOT mats is cycled for 11 000 times with 80% capacitance retention. After forty 125 kJ m−2 impacts, capacitance degrades by 6% and 1D electrode architecture remains.
featured image: by controlling the formation of rust in solution, researchers in Arts & Sciences grew a micrometer-thick porous mat of conducting fibers affixed to a soft, pliable layer of organic plastic. This new energy storage device can withstand a hammer striking it more than 40 times. (Image: D’Arcy laboratory / Washington University)
