Polymer capacitors replaced electrolytic aluminum and manganese tantalum capacitors in many applications. While this trend was driven mainly by low equivalent series resistance (ESR) requirements in the past, high reliability performance is additionally requested for polymer capacitors nowadays. The development of new conductive polymers has opened the field of high reliability applications for polymer capacitors such as automotive, space and telecommunication. Even in consumer electronics, a trend to design in polymer capacitors having a higher reliability can be seen.
This paper presents the superior performance of new conductive polymer materials regarding harsh conditions such as elevated temperature and high humidity. State-of-the-art conductive polymers can not only achieve an intrinsically higher reliability but being much more environmentally friendly compared to previous polymer technologies.
For more than 25 years, applications of polymer aluminum and tantalum capacitors have been driven by low ESR requirements. Traditional electrolytic capacitors were not able to meet these requirements of modern electronic circuits like motherboards. However, the application field of polymer capacitors was limited to consumer electronics mainly due to the lack of high voltage capability, relatively high DC leakage current (DCL) and low reliability performance.
During the last decade, these restrictions of polymer capacitors have been overcome and high voltage, low DCL and high reliability applications could be accessed. The rated voltage range of polymer capacitors has been extended from maximum of about 25 V to 400 V. In combination with a superior DCL performance, the new polymer capacitors have been introduced in high reliability applications such as automotive and space.
While the COVID-19 pandemic has given an additional boost to the demand from consumer electronics in 2020/21, a strong and steady growth is emerging from automotive, communication infrastructure and industrial applications.
For capacitors used in such applications, the trend towards lower ESR, higher voltages and a higher capacitance density is ongoing and additionally a much higher reliability is needed. Life-time requirement can be as long as 10 years at a 100% duty cycle for telecommunication infrastructure. Temperature ratings of more than 150°C are requested in automotive. A high stability at harsh conditions like 85°C/85% relative humidity (RH) is necessary when for example air conditioning and cooling of data centers are omitted for energy saving reasons.
The development of conductive polymer dispersions for capacitor application paved the way for polymer capacitors to enter high reliability applications. Further material improvement is necessary to cope with future reliability requirements.
CONDUCTIVE POLYMERS’ EVOLUTION
Conductive polymers are applied as cathode material in electrolytic capacitors to achieve low ESR (Fig. 1). Traditional cathode materials like liquid electrolytes or manganese dioxide have orders of magnitude lower conductivity.
For aluminum and tantalum capacitors, a conductive polymer film is deposited by chemical in-situ polymerization of the monomer 3,4-ethylenedioxythiophene (EDOT) or from PEDOT:PSS conductive polymer dispersions on the dielectric which was formed by anodization of a porous aluminum or tantalum electrode (Fig. 2).
When conductive polymer dispersions are applied, the manufacturing process of polymer capacitors can be significantly simplified compared to in-situ polymerization by a dip and dry process without any chemical reactions. Furthermore, conductive polymer dispersions are water-borne and therefore environmentally friendly compared to organic solvent-based precursors for in-situ polymerization.
Besides process and environmental aspects, capacitors made with conductive polymer dispersions exhibit significant performance advantages over those for which an in-situ chemical process is applied.
The by far superior voltage performance is the most striking difference. With in-situ polymerization, voltage ratings only up to about 35V can be realized in an acceptable quality, while 400V is achieved with polymer dispersion. The difference in performance is attributed to the particle nature of the polymer dispersions. In contrary to molecules used for in-situ polymerization, such particles cannot enter pinholes in the dielectric and do not deteriorate the break-down voltage (BDV) of the dielectric.